المؤلفون: Jack L. Sutro, Alois Fürstner

مصطلحات موضوعية: Biophysics, Biochemistry, Microbiology, Molecular Biology, Evolutionary Biology, Infectious Diseases, Virology, − pmb group, strategic role beyond, mere safeguarding function, longest linear sequence, latent hydride source, impose high selectivity, gold catalyzed rearrangement, projected total synthesis, total synthesis, unconventional timing, stereoconvergent character, signature cycloallene, ring strain, required substrate, new air, made possible, macrocyclic frame, late stage, last step, actual fact

Relation: https://figshare.com/articles/journal_contribution/Total_Synthesis_of_the_Allenic_Macrolide_-Archangiumide/25029478

الاتاحة: https://doi.org/10.1021/jacs.3c13304.s001
https://figshare.com/articles/journal_contribution/Total_Synthesis_of_the_Allenic_Macrolide_-Archangiumide/25029478

المؤلفون: Philip Boehm (4775676), Elliott H. Denton (9395675), Joel Wick (14327907), Bill Morandi (1368567)

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Microbiology, Genetics, Molecular Biology, Biotechnology, Inorganic Chemistry, Space Science, Biological Sciences not elsewhere classified, catalyzed intermolecular synthesis, 6 , co )< sub, solid co surrogate, commercially available alkynes, co surrogate, wide range, vinyl iodides, vinyl iodide, substituted cyclopentenones, step sequence, polysubstituted cyclopentenones, internal alkynes, hydride source, functional groups, carbon framework

Relation: https://figshare.com/articles/journal_contribution/Intermolecular_Pauson_Khand-Type_Reaction_of_Vinyl_Iodides_with_Alkynes_and_a_CO_Surrogate/21815226

الاتاحة: https://doi.org/10.1021/acs.joc.2c02465.s001

المؤلفون: Li-Ming Yin (10835634), Meng-Chan Sun (11945124), Xiao-Ju Si (6287384), Dandan Yang (291423), Mao-Ping Song (1533073), Jun-Long Niu (1533061)

مصطلحات موضوعية: Biochemistry, Genetics, Biotechnology, Cancer, Infectious Diseases, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, mechanistic studies indicated, even nonfluorinated substrates, difluoroalkyl radical might, commercially available cf, >- markovnikov regioselectivity, >- markovnikov hydrodifluoroalkylation, highly remote alkenes, 3 , 2 , anti <, unactivated alkenes, simple alkenes, wide range, using phsih, mild conditions, key intermediate, hydride source, efficient ni, drug molecules, catalyzed hydrodifluoroalkylation

Relation: https://figshare.com/articles/journal_contribution/Nickel-Catalyzed_i_anti_i_-Markovnikov_Hydrodifluoroalkylation_of_Unactivated_Alkenes/18857896

الاتاحة: https://doi.org/10.1021/acs.orglett.1c04346.s001

المؤلفون: Xiaohan Li (276434), Karthik S. Iyer (11377920), Ruchita R. Thakore (8123387), David K. Leahy (2042089), J. Daniel Bailey (2362969), Bruce H. Lipshutz (1330881)

مصطلحات موضوعية: Biochemistry, Molecular Biology, Pharmacology, Sociology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, stoichiometric hydride source, readily available α, bisulfite addition compounds, aqueous reaction medium, several applications, reductive aminations, picolineborane serves, pharmaceutical industry, easily accomplished

Relation: https://figshare.com/articles/journal_contribution/Bisulfite_Addition_Compounds_as_Substrates_for_Reductive_Aminations_in_Water/16560162

الاتاحة: https://doi.org/10.1021/acs.orglett.1c02604.s001

المؤلفون: Hai N. Tran (2142808), Levi M. Stanley (1329015)

مصطلحات موضوعية: Biochemistry, Medicine, Microbiology, Cell Biology, Molecular Biology, Pharmacology, Immunology, Virology, Computational Biology, Space Science, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, ensuring fast transmetalation, achieve high enantioselectivities, 4 , 2 , various vinylarenes react, nonracemic nickel catalyst, catalyzed enantioselective hydroboration, enantioselective hydroboration, vinylarenes catalyzed, hydride source, facile method

Relation: https://figshare.com/articles/journal_contribution/Nickel-Catalyzed_Enantioselective_Hydroboration_of_Vinylarenes/17203513

الاتاحة: https://doi.org/10.1021/acs.orglett.1c04073.s001

المؤلفون: Chen-Fei Liu (6089834), Xiaohua Luo (4845202), Hongyu Wang (366946), Ming Joo Koh (1409977)

مصطلحات موضوعية: Biochemistry, Microbiology, Biotechnology, Evolutionary Biology, Infectious Diseases, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Catalytic, metal-hydride atom transfer, Markovnikov-selective, ratio, organo bromides, hydride source, branched-selective examples, nonradical reaction pathway, triflate, unactivated olefins, bond, Regioselective, chemical transformations, scaffold, exogenous alkoxide base, aryl, evidence points, cocatalyst, Ni, quaternary centers, Sequential Carbonickelation-Hydride., Olefin, utility

Relation: https://figshare.com/articles/journal_contribution/Catalytic_Regioselective_Olefin_Hydroarylation_alkenylation_by_Sequential_Carbonickelation-Hydride_Transfer/14815829

الاتاحة: https://doi.org/10.1021/jacs.1c03228.s001

المؤلفون: Nicolas Joly (10676528), Léo Bettoni (6630020), Sylvain Gaillard (18117), Albert Poater (1377699), Jean-Luc Renaud (1756909)

مصطلحات موضوعية: Biochemistry, Microbiology, Molecular Biology, Biotechnology, Cancer, Chemical Sciences not elsewhere classified, origin, Dialkylated Acyl Hydrazides, Phosphine-Free Ruthenium Complex-Ca., presence, experiment, calculation, threshold, borrowing hydrogen strategy, Density, hydride source, diaminocyclopentadienone ruthenium ., cascade process, DFT, dialkylation, dialkylated acyl hydrazide compounds, Mono, Deuterium, alkylating reagents, Hydrogen Strategy Herein

Relation: https://figshare.com/articles/journal_contribution/Phosphine-Free_Ruthenium_Complex-Catalyzed_Synthesis_of_Mono-_or_Dialkylated_Acyl_Hydrazides_via_the_Borrowing_Hydrogen_Strategy/14456303

الاتاحة: https://doi.org/10.1021/acs.joc.1c00654.s001

المؤلفون: David M. Fialho (10710269), Elham Etemadi-Davan (656131), Olivia C. Langner (10710272), Balaram S. Takale (4573450), Amol Gadakh (10710275), Ganesh Sambasivam (10710278), Bruce H. Lipshutz (1330881)

مصطلحات موضوعية: Biochemistry, Medicine, Pharmacology, Biotechnology, Cancer, Mental Health, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, alcohol products, Mild Aqueous Micellar Conditions En., micellar medium, Copper-Catalyzed Asymmetric Reductions, stoichiometric hydride source, access enantio-enriched alcohols, ee values, base metal catalyst, PMHS

Relation: https://figshare.com/articles/journal_contribution/Copper-Catalyzed_Asymmetric_Reductions_of_Aryl_Heteroaryl_Ketones_under_Mild_Aqueous_Micellar_Conditions/14495405

الاتاحة: https://doi.org/10.1021/acs.orglett.1c00746.s001

المؤلفون: Hualing He (10144416), Xiaoxue Tang (4168471), Yang Cao (53545), Jon C. Antilla (1334853)

مصطلحات موضوعية: Biochemistry, Molecular Biology, Biotechnology, Sociology, Developmental Biology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, ee, Imine, Catecholborane, Catalytic Asymmetric Reduction, Trifluoromethylated, synthetically, hydride source, enantioselective reduction, method, enantioselectivitie, BINOL-derived boro-phosphate, BINOL-Derived Boro-phosphates, α- trifluoromethylated imines, chiral α- trifluoromethylated amines, yield

Relation: https://figshare.com/articles/journal_contribution/Catalytic_Asymmetric_Reduction_of_Trifluoromethylated_Imines_with_Catecholborane_by_BINOL-Derived_Boro-phosphates/14035467

الاتاحة: https://doi.org/10.1021/acs.joc.0c03009.s001

المؤلفون: Barnala Raveendra, Braja Gopal Das, Prasanta Ghorai

مصطلحات موضوعية: Biophysics, Biochemistry, Genetics, Biotechnology, Evolutionary Biology, Developmental Biology, Cancer, Mental Health, Plant Biology, Computational Biology, Physical Sciences not elsewhere classified, tertiary amine moiety, corresponding alkoxyboronate intermediates, unprecedented strategy, substituted 1, readily prepared, proton source, new strategy, michael reaction, intramolecular oxa, hydride source, enantioenriched 1

Relation: https://figshare.com/articles/journal_contribution/Organocatalytic_Enantioselective_Intramolecular_Oxa_Michael_Reaction_of_Alkoxyboronate_A_New_Strategy_for_Enantioenriched_1_Substituted_1_3_Dihydroisobenzofurans/2237929

الاتاحة: https://doi.org/10.1021/ol502614n.s001
https://figshare.com/articles/journal_contribution/Organocatalytic_Enantioselective_Intramolecular_Oxa_Michael_Reaction_of_Alkoxyboronate_A_New_Strategy_for_Enantioenriched_1_Substituted_1_3_Dihydroisobenzofurans/2237929

المؤلفون: Barnala Raveendra, Braja Gopal Das, Prasanta Ghorai

مصطلحات موضوعية: Biophysics, Biochemistry, Genetics, Biotechnology, Evolutionary Biology, Developmental Biology, Cancer, Mental Health, Plant Biology, Computational Biology, Physical Sciences not elsewhere classified, tertiary amine moiety, corresponding alkoxyboronate intermediates, unprecedented strategy, substituted 1, readily prepared, proton source, new strategy, michael reaction, intramolecular oxa, hydride source, enantioenriched 1

Relation: https://figshare.com/articles/journal_contribution/Organocatalytic_Enantioselective_Intramolecular_Oxa_Michael_Reaction_of_Alkoxyboronate_A_New_Strategy_for_Enantioenriched_1_Substituted_1_3_Dihydroisobenzofurans/2237932

الاتاحة: https://doi.org/10.1021/ol502614n.s002
https://figshare.com/articles/journal_contribution/Organocatalytic_Enantioselective_Intramolecular_Oxa_Michael_Reaction_of_Alkoxyboronate_A_New_Strategy_for_Enantioenriched_1_Substituted_1_3_Dihydroisobenzofurans/2237932

المؤلفون: Johannes Kleinheider, Christoph Schwab, Carsten Strohmann

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Microbiology, Molecular Biology, Pharmacology, Sociology, Plant Biology, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, quantum chemical calculations, applications results mostly, asymmetric alkyllithium syntheses, lithium hydride addition, alkyl anion could, alkyl anion, alkyllithium reagents, reaction could, hydride source, hydride elimination, wide range, situ <, sec <, reliably identified, reaction mechanism, ms analysis, hidden source, ftir spectroscopy

Relation: https://figshare.com/articles/journal_contribution/Alkyllithium_Reagents_as_a_Hidden_Source_of_Lithium_Hydride/24514348

الاتاحة: https://doi.org/10.1021/acs.organomet.3c00405.s001
https://figshare.com/articles/journal_contribution/Alkyllithium_Reagents_as_a_Hidden_Source_of_Lithium_Hydride/24514348