المؤلفون: Gayathri B. Gange (11126507), Amanda L. Humphries (11126510), Dmitry E. Royzman (11126513), Mark D. Smith (1406332), Dmitry V. Peryshkov (1425691)

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Physiology, Pharmacology, Evolutionary Biology, Cancer, Computational Biology, Mathematical Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, binding sites, C 2 B 10 H 10, phosphine groups, group element system, report metal-free bond activation, Carboranyl Diphosphines, oxidative addition, two-electron redox states, metal-free bond activation, carboranyl diphosphine 1- P t Bu 2 ., transition metal centers, electron-donating exohedral substit., electron-accepting cluster, group hydrides, boron cage

Relation: https://figshare.com/articles/journal_contribution/Metal-Free_Bond_Activation_by_Carboranyl_Diphosphines/14974931

الاتاحة: https://doi.org/10.1021/jacs.1c05387.s001

المؤلفون: Sara Bonfante, Christian Lorber, Jason M. Lynam, Antoine Simonneau, John M. Slattery

مصطلحات موضوعية: Biochemistry, Medicine, Computational Biology, use external oxidizing, scarce precious metals, readily available commercially, many classical transition, like transition state, group element system, fluoroaromatic substrate via, enforce unusual geometries, p ­( v, p ­( iii, undergoes reductive elimination, mechanistically metallomimetic behavior, replace expensive, reducing agents, realistic prospect, reagents used, rare example, pseudotransmetalation step, possible using, phosphine catalyst, oxidation states, mild conditions, metallomimetic catalysis, industrial settings, hydridosilicate counterion, hydride transfer, highly desirable

Relation: https://figshare.com/articles/journal_contribution/Metallomimetic_C_F_Activation_Catalysis_by_Simple_Phosphines/24986101

الاتاحة: https://doi.org/10.1021/jacs.3c10614.s001
https://figshare.com/articles/journal_contribution/Metallomimetic_C_F_Activation_Catalysis_by_Simple_Phosphines/24986101