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1Academic JournalProbing the Size Limit of Dispersion Energy Donors with a Bifluorenylidene Balance: Magic Cyclohexyl
المؤلفون: Finn M. Wilming (11679953), Benito Marazzi (14307868), Paul P. Debes (14307871), Jonathan Becker (1872742), Peter R. Schreiner (770003)
مصطلحات موضوعية: Biophysics, Biochemistry, Physiology, Sociology, Mental Health, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, “ folded ”, substituted system shows, london dispersion interactions, equilibrium shift toward, dispersion energy donors, 9 ′- bifluorenylidenes, 333 k using, 05 kcal mol, demanding substituents like, close relative position, 6 ± 0, seven organic solvents, >- isomer due, cyclohexyl groups paired, e sub, 1 sup, e <, >- isomer, − 0, functional groups, close proximity, aryl substituents
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2Academic Journal
مصطلحات موضوعية: Biophysics, Biochemistry, Genetics, Science Policy, Mental Health, Biological Sciences not elsewhere classified, raw group polarizabilities, experimentally relevant settings, dispersion energy donors, attractive london dispersion, two competing interactions, negligible ld part, complementary steric scale, steric hindrance, steric factor, steric effects, steric demands, thereby providing, quantitatively comparable, monosubstituted cyclohexanes, minimize strain, ld interactions, electrostatic interactions, distances found, direct comparisons, ded scale, considered purely, computational study, common assumption, charge transfer
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3Academic Journal