المؤلفون: Qigang Zhong, Jannis Jung, Daniel Kohrs, L. Alix Kaczmarek, Daniel Ebeling, Doreen Mollenhauer, Hermann A. Wegner, André Schirmeisen

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Molecular Biology, Biotechnology, Infectious Diseases, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, well understood due, radical addition ), fabricating various low, dimensional covalent nanostructures, dft calculations allow, conventional solution chemistry, comprehensive theoretical analysis, demanding initiation step, harsh reaction conditions, aryl sub, catalyzed h shift, predominant cyclized intermediates, h shift, determining step, cyclized intermediates, room temperature, reaction thermodynamics, powerful approach, microscopic insights, intermediates correspond, fleetingly existing

Relation: https://figshare.com/articles/journal_contribution/Deciphering_the_Mechanism_of_On-Surface_Dehydrogenative_C_C_Coupling_Reactions/25003045

الاتاحة: https://doi.org/10.1021/jacs.3c05233.s001
https://figshare.com/articles/journal_contribution/Deciphering_the_Mechanism_of_On-Surface_Dehydrogenative_C_C_Coupling_Reactions/25003045

المؤلفون: Sara Fernández-Moyano (11412839), Marconi N. Peñas-Defrutos (11412842), Camino Bartolomé (2256205), Pablo Espinet (1569922)

مصطلحات موضوعية: Biophysics, Biochemistry, Cell Biology, Genetics, Immunology, Space Science, Physical Sciences not elsewhere classified, pseudooctahedral geometry lead, concepts trans influence, cis influence analysis, aryl sub, 5 sub, shows typical metal,  c , name side donations, iii , metal complexes since, side donations, – c, rich variety, planar systems, nonorthogonal arrangement, multiple contributions, escaped detection, easily account, cyclopentadienyl transition, continuous popularity, bonding contributions, also observed

Relation: https://figshare.com/articles/journal_contribution/Expanding_the_Concepts_Trans_Influence_and_Back-Donation_Hybrid_and_Side_Donations_in_Cp_M_sup_III_sup_L_XY_M_Rh_Ir_Complexes_with_CO_CN_sup_sup_and_CNR_Ligands_A_Window_to_Cis_Influence/16594763

الاتاحة: https://doi.org/10.1021/acs.inorgchem.1c02189.s001

المؤلفون: Agata Szlapa-Kula (7471373), Magdalena Małecka (1444498), Anna M. Maroń (11773714), Henryk Janeczek (1323525), Mariola Siwy (1900369), Ewa Schab-Balcerzak (1323546), Marcin Szalkowski (7471379), Sebastian Maćkowski (1357209), Tomasz Pedzinski (828144), Karol Erfurt (7924946), Barbara Machura (1605796)

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Pharmacology, Space Science, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, weak electronic coupling, noticeable red shift, low lying relative, nanosecond transient absorption, molar absorption coefficients, temperature emission lifetimes, resolved emission spectroscopy, naphthyl -, appended aryl group, eight rhenium ­(, 3 , naphthyl )- terpy, lowest energy absorption, aryl sub, yl )­ pyridine, pyrenyl )- terpy, complexes incorporating 2, il /< sup, triplet mlct state, ilct excited states

Time: 9, 2

Relation: https://figshare.com/articles/journal_contribution/In-Depth_Studies_of_Ground-_and_Excited-State_Properties_of_Re_I_Carbonyl_Complexes_Bearing_2_2_6_2_-Terpyridine_and_2_6-Bis_pyrazin-2-yl_pyridine_Coupled_with_Conjugated_Aryl_Chromophores/17102731

الاتاحة: https://doi.org/10.1021/acs.inorgchem.1c02151.s001

المؤلفون: Sara Fernández-Moyano (11412839), Marconi N. Peñas-Defrutos (11412842), Camino Bartolomé (2256205), Pablo Espinet (1569922)

مصطلحات موضوعية: Biophysics, Biochemistry, Cell Biology, Genetics, Immunology, Space Science, Physical Sciences not elsewhere classified, pseudooctahedral geometry lead, concepts trans influence, cis influence analysis, aryl sub, 5 sub, shows typical metal,  c , name side donations, iii , metal complexes since, side donations, – c, rich variety, planar systems, nonorthogonal arrangement, multiple contributions, escaped detection, easily account, cyclopentadienyl transition, continuous popularity, bonding contributions, also observed

Relation: https://figshare.com/articles/dataset/Expanding_the_Concepts_Trans_Influence_and_Back-Donation_Hybrid_and_Side_Donations_in_Cp_M_sup_III_sup_L_XY_M_Rh_Ir_Complexes_with_CO_CN_sup_sup_and_CNR_Ligands_A_Window_to_Cis_Influence/16594766

الاتاحة: https://doi.org/10.1021/acs.inorgchem.1c02189.s002

المؤلفون: Fedor M. Miloserdov (1701553), Anne-Frédérique Pécharman (1625953), Lia Sotorrios (11575982), Nasir A. Rajabi (1561750), John P. Lowe (1309878), Stuart A. Macgregor (1350846), Mary F. Mahon (1293876), Michael K. Whittlesey (1309881)

مصطلحات موضوعية: Biophysics, Biochemistry, Cell Biology, Genetics, Neuroscience, Chemical Sciences not elsewhere classified, feature bridging hydrides, cyclometalated phosphine ligand, biased toward ru, 5 -( cf, aryl sub, 6 sub, 4 sub, 3 sub, 2 sub, b ­{ 3, 7 , 3 , 2 , 12 , computational analyses indicate, cationic trihydride complex, show diverse reactivity, ru ­( pph, n , cationic heterobimetallic ruzn, (< b, computational study, undergoes pph, lewis bases

Relation: https://figshare.com/articles/dataset/Bonding_and_Reactivity_of_a_Pair_of_Neutral_and_Cationic_Heterobimetallic_RuZn_sub_2_sub_Complexes/16826000

الاتاحة: https://doi.org/10.1021/acs.inorgchem.1c02072.s002

المؤلفون: Matthias D. Böhme, Sebastian Termühlen, Patrick D. Dutschke, Alexander Hepp, F. Ekkehardt Hahn

مصطلحات موضوعية: Biochemistry, Genetics, Immunology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, density functional theory, computational study depending, chelate ring present, >- tolyl ,<, >- methyl group, >- mesityl -<, membered chelate ring, n ′- substituents, c chelate ring, aryl sub, alkyl sub, iii , nhc undergo sp, >- benzyl, n <, membered c, ortho <, aromatic n, various reactions, useful catalysts, studies corroborated, mes substituent, cyclometalated complexes, complexes bearing, complex reacts

Relation: https://figshare.com/articles/journal_contribution/Formation_of_C_sub_NHC_sub_sup_sup_C_sub_alkyl_sub_and_C_sub_NHC_sub_sup_sup_C_sub_aryl_sub_sup_2_sup_Chelate_Complexes_through_Competitive_sp_sup_3_sup_-_and_sp_sup_2_sup_CH_Activations_An_Experimental_and_Computational_Study/24746994

الاتاحة: https://doi.org/10.1021/acsomega.3c08427.s001
https://figshare.com/articles/journal_contribution/Formation_of_C_sub_NHC_sub_sup_sup_C_sub_alkyl_sub_and_C_sub_NHC_sub_sup_sup_C_sub_aryl_sub_sup_2_sup_Chelate_Complexes_through_Competitive_sp_sup_3_sup_-_and_sp_sup_2_sup_CH_Activations_An_Experimental_and_Computational_Study/24746994

المؤلفون: Matthias D. Böhme, Sebastian Termühlen, Patrick D. Dutschke, Alexander Hepp, F. Ekkehardt Hahn

مصطلحات موضوعية: Biochemistry, Genetics, Immunology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, density functional theory, computational study depending, chelate ring present, >- tolyl ,<, >- methyl group, >- mesityl -<, membered chelate ring, n ′- substituents, c chelate ring, aryl sub, alkyl sub, iii , nhc undergo sp, >- benzyl, n <, membered c, ortho <, aromatic n, various reactions, useful catalysts, studies corroborated, mes substituent, cyclometalated complexes, complexes bearing, complex reacts

Relation: https://figshare.com/articles/dataset/Formation_of_C_sub_NHC_sub_sup_sup_C_sub_alkyl_sub_and_C_sub_NHC_sub_sup_sup_C_sub_aryl_sub_sup_2_sup_Chelate_Complexes_through_Competitive_sp_sup_3_sup_-_and_sp_sup_2_sup_CH_Activations_An_Experimental_and_Computational_Study/24746997

الاتاحة: https://doi.org/10.1021/acsomega.3c08427.s002
https://figshare.com/articles/dataset/Formation_of_C_sub_NHC_sub_sup_sup_C_sub_alkyl_sub_and_C_sub_NHC_sub_sup_sup_C_sub_aryl_sub_sup_2_sup_Chelate_Complexes_through_Competitive_sp_sup_3_sup_-_and_sp_sup_2_sup_CH_Activations_An_Experimental_and_Computational_Study/24746997

المؤلفون: Matthias D. Böhme, Sebastian Termühlen, Patrick D. Dutschke, Alexander Hepp, F. Ekkehardt Hahn

مصطلحات موضوعية: Biochemistry, Genetics, Immunology, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, density functional theory, computational study depending, chelate ring present, >- tolyl ,<, >- methyl group, >- mesityl -<, membered chelate ring, n ′- substituents, c chelate ring, aryl sub, alkyl sub, iii , nhc undergo sp, >- benzyl, n <, membered c, ortho <, aromatic n, various reactions, useful catalysts, studies corroborated, mes substituent, cyclometalated complexes, complexes bearing, complex reacts

Relation: https://figshare.com/articles/dataset/Formation_of_C_sub_NHC_sub_sup_sup_C_sub_alkyl_sub_and_C_sub_NHC_sub_sup_sup_C_sub_aryl_sub_sup_2_sup_Chelate_Complexes_through_Competitive_sp_sup_3_sup_-_and_sp_sup_2_sup_CH_Activations_An_Experimental_and_Computational_Study/24747000

الاتاحة: https://doi.org/10.1021/acsomega.3c08427.s003
https://figshare.com/articles/dataset/Formation_of_C_sub_NHC_sub_sup_sup_C_sub_alkyl_sub_and_C_sub_NHC_sub_sup_sup_C_sub_aryl_sub_sup_2_sup_Chelate_Complexes_through_Competitive_sp_sup_3_sup_-_and_sp_sup_2_sup_CH_Activations_An_Experimental_and_Computational_Study/24747000