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1
المؤلفون: Luc Neuville, Jieping Zhu, Thibaud Gerfaud
المساهمون: Institut de Chimie des Substances Naturelles (ICSN), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)
المصدر: Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2009, 48 (3), pp.572-7. ⟨10.1002/anie.200804683⟩مصطلحات موضوعية: Annulation, chemistry.chemical_element, [SDV.BC]Life Sciences [q-bio]/Cellular Biology, phenanthridine prepn, isoquinoline prepn, acyloxime prepn aryne annulation palladium, 010402 general chemistry, Aryne, 01 natural sciences, Catalysis, Domino, chemistry.chemical_compound, PREP (Preparation), Butyronitrile, Organic chemistry, Domino process, ComputingMilieux_MISCELLANEOUS, RACT (Reactant or reagent) (arynes, prepn. of phenanthridines and isoquinolines via palladium-catalyzed annulation of acyloximes with in situ generated benzyne from silylphenyl triflates), Cyclization (prepn. of phenanthridines and isoquinolines via palladium-catalyzed annulation of acyloximes with in situ generated benzyne from silylphenyl triflates), Chemistry, 010405 organic chemistry, SPN (Synthetic preparation), General Chemistry, General Medicine, Oxime, 3. Good health, 0104 chemical sciences, and their use in prepn. of phenanthridines and isoquinolines), Alkynes, Aromatic hydrocarbons Role: RCT (Reactant), RACT (Reactant or reagent) (aryl, prepn. of pentafluorobenzoyl oximes via condensation of ketones with hydroxyamine followed by esterification with pentafluorobenzoyl chloride, Ketones Role: RCT (Reactant), Palladium
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2
المؤلفون: Manfred Schlosser, Eva Castagnetti
مصطلحات موضوعية: 2-didehydro-3- or -4-(trifluoromethoxy)benzene and its conversion to trifluoromethoxynaphthalenes), Organic Chemistry, Regioselectivity, SPN (Synthetic preparation), Medicinal chemistry, Lithium diisopropylamide, Aryne, Alkynes, Aromatic hydrocarbons Role: RCT (Reactant), chemistry.chemical_compound, chemistry, RACT (Reactant or reagent) (arynes, prepn. of 1, Furan, PREP (Preparation), Butyllithium, Organic chemistry, Physical and Theoretical Chemistry, Benzene, Isomerization, bromotrifluoromethoxybenzene lithiation trapping furan, benzene bromotrifluoromethoxy lithiation trapping furan, epoxynaphthalene prepn ring cleavage bromination, naphthol trifluoromethoxy prepn, naphthalenecarboxylic acid trifluoromethoxy prepn, Phenyllithium