يعرض 1 - 20 نتائج من 31 نتيجة بحث عن '"Nanotubos de titanato"', وقت الاستعلام: 0.88s تنقيح النتائج
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    وصف الملف: 1 - 16; application/pdf

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Gl¨ aser, Selective oxidation of 5-hydroxymethylfurfural to 2,5- diformylfuran by visible light-driven photocatalysis over in situ substratesensitized titania, ChemSusChem 14 (2021) 1351–1362, https://doi.org/10.1002/ cssc.202002687.; H. Kobayashi, S. Higashimoto, DFT study on the reaction mechanisms behind the catalytic oxidation of benzyl alcohol into benzaldehyde by O2 over anatase TiO2 surfaces with hydroxyl groups: role of visible-light irradiation, Appl. Catal. B: Environ. 170– 171 (2015) 135–143, https://doi.org/10.1016/j. apcatb.2015.01.035.; X. Yan, Y. Li, T. Xia, Black titanium dioxide nanomaterials in photocatalysis, Int. J. Photo 2017 (2017), https://doi.org/10.1155/2017/8529851.; A. Naldoni, M. Altomare, G. Zoppellaro, N. Liu, S. ˇ Kment, R. Zboˇril, P. Schmuki, Photocatalysis with reduced TiO 2: From Black TiO 2 to cocatalyst-free hydrogen production, ACS Catal. 9 (2019) 345–364, https://doi.org/10.1021/ acscatal.8b04068.; B. Ohtani, O.O. Prieto-Mahaney, D. Li, R. 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B: Environ. 174 (2015) 96–104, https://doi.org/10.1016/j.apcatb.2015.02.028.; https://doi.org/10.1016/j.apcatb.2022.121939; https://hdl.handle.net/20.500.12494/52377; Dimitrios A. Giannakoudakis, Abdul Qayyum, Mariusz Barczak, Ramón Fernando Colmenares-Quintero, Piotr Borowski, Konstantinos Triantafyllidis, Juan Carlos Colmenares, Mechanistic and kinetic studies of benzyl alcohol photocatalytic oxidation by nanostructured titanium (hydro)oxides: Do we know the entire story?, Applied Catalysis B: Environmental, Volume 320, 2023, 121939, ISSN 0926-3373, https://doi.org/10.1016/j.apcatb.2022.121939. (https://www.sciencedirect.com/science/article/pii/S0926337322008803) Abstract: Selective upgrade of lignocellulosic biomass-derived aromatic compounds by photocatalytic oxidation is assumed as a prosperous, environmentally friendly, and cost-effective process. We present for the first time the application of various advantageous titanium oxide nano-photocatalysts for the additives-free selective partial oxidation of benzyl alcohol to benzaldehyde at ambient conditions. The two best-performing materials were found titanate nanotubes and nanocores of anatase surrounded by amorphous titanium hydroxide phase. The results obtained by scavenger tests on top of the DFT calculations led us to conclude that various reactions and active species are responsible by a complex way for materials’ photoreactivity. Depending on nanocatalysts’ physicochemical features as well as the light irradiation (ultraviolet vs. royal-blue), different mechanisms/oxidation-pathways are photo-catalyzed. Finally, we show that utilizing organic compounds like benzoquinone as scavenger hides risks due to the interactions with the targeted to be converted organic that results in elevated photolytic decomposition even under royal-blue light. Keywords: Biomass valorization; Photocatalysis; Benzyl alcohol oxidation; Benzaldehyde; TiO2 nanomaterials; Titanate nanotubes; DIMITRIOS A GIANNAKOUDAKIS, ABDUL QAYUUM, MARIUSZ BARCZAK, RAMON FERNANDO COLMENARES QUINTERO, PIOTR BOROWSKI, KONSTANTINOS TRIANTAFYLLIDIS, JUAN CARLOS COLMENARES QUINTERO, "Mechanistic and kinetic studies of benzyl alcohol photocatalytic oxidation by nanostructured titanium (hydro)oxides: do we know the entire story?" . En: Países Bajos Applied Catalysis B: Environmental ISSN: 0926-3373 ed: Elsevier Science Bv v.320 fasc.N/A p.1 - 54 ,2022, DOI:10.1016/j.apcatb.2022.121939

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    المساهمون: Angulo Paredes, Yolanda Del Rocío

    Relation: Villarroel Estévez, Natalia Yessenia (2020). Síntesis y recubrimiento del polímero poly(p-phenylene-terephthalamide) (PPTA) con nanomateriales para el posible refuerzo de prototipos de chalecos antibalas. Carrera de Ingeniería en Biotecnología. Universidad de las Fuerzas Armadas ESPE. Matriz Sangolquí; 044123; http://repositorio.espe.edu.ec/handle/21000/23395

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    مصطلحات موضوعية: Nanocompuesto, nanotubos de titanato, Polímeros

    Relation: Carrillo Rodríguez, M. G. Desarrollo de un material compuesto de matriz de polietileno de alta densidad reforzado con nanotubos de titanato. 58. Quito : EPN.; T-IQ 1031/CD-7298; http://bibdigital.epn.edu.ec/handle/15000/16704

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