المؤلفون: Sennari, Goh, Yamagishi, Hiroki, Sarpong, Richmond

المصدر: Chemistry Letters. 53(11)

مصطلحات موضوعية: Organic Chemistry, Chemical Sciences, C-H metalation, hydrogen-atom abstraction, C–H metalation, General Chemistry, Chemical sciences

وصف الملف: application/pdf

URL الوصول: https://escholarship.org/uc/item/4p50k5qn
https://escholarship.org/content/qt4p50k5qn/qt4p50k5qn.pdf

المؤلفون: Xiao-Rui Ren, Kang Xing, Teng Liu, Ronghui Cao, Li-Long Dang, Feng Bai, Peng-Cheng Duan

المصدر: Molecules, Vol 29, Iss 14, p 3424 (2024)

مصطلحات موضوعية: hydrogen atom abstraction, reduction, thiaporphyrins, X-ray diffraction, ZINDO/S calculation, Organic chemistry, QD241-441

وصف الملف: electronic resource

Relation: https://www.mdpi.com/1420-3049/29/14/3424; https://doaj.org/toc/1420-3049

URL الوصول: https://doaj.org/article/adc46f320d2f498fb4ca351ebbf05088

المؤلفون: Jing Chen, Tingting Yang, Sushan Feng, Leiyu Wang, Jianhui Xie, Yingying Liu

مصطلحات موضوعية: Biophysics, Biochemistry, Cell Biology, Genetics, Molecular Biology, Physiology, Pharmacology, Biotechnology, Cancer, Chemical Sciences not elsewhere classified, yl )- 2, hydrogen atom abstraction, high coordination numbers, bond dissociation energies, 3 ± 0, 2 ′- bipyridine, 2 ± 0, 2 , catalytic oxidation chemistry, 6 ′- di, 2 +, ), 4 , oxo complex ruthenium, oxo complex, >< sub, (< b, h <, oxo species, rate constants

Relation: https://figshare.com/articles/journal_contribution/C_H_Bond_Activation_by_a_Seven-Coordinate_Bipyridine_Bipyrazole_Ruthenium_IV_Oxo_Complex/25321161

الاتاحة: https://doi.org/10.1021/acs.inorgchem.4c00223.s001
https://figshare.com/articles/journal_contribution/C_H_Bond_Activation_by_a_Seven-Coordinate_Bipyridine_Bipyrazole_Ruthenium_IV_Oxo_Complex/25321161

المؤلفون: Zhiwei Deng, Hao Su, Xiaodong Hou, Huibin Xu, Zhenbo Yuan, Xiang Sheng, Yijian Rao

مصطلحات موضوعية: Biophysics, Biochemistry, Microbiology, Biotechnology, Developmental Biology, Hematology, Computational Biology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, hydrogen atom abstraction, four histidine residues, btg13 remains elusive, rare iron coordination, atypical nonheme iron, kcx could increase, bond cleavage processes, 10 , dependent dioxygenase btg13, bond cleavage, dependent oxygenases, ferrous iron, thereby boosting, study advances, results reveal, recently reported, reactions catalyzed, reaction mechanism, oxygen rebound, mechanistic investigation

Relation: https://figshare.com/articles/journal_contribution/Mechanistic_Investigation_on_C_C_Bond_Cleavage_of_Anthraquinone_Catalyzed_by_an_Atypical_Nonheme_Iron-Dependent_Dioxygenase_BTG13/24935729

الاتاحة: https://doi.org/10.1021/acscatal.3c04053.s001
https://figshare.com/articles/journal_contribution/Mechanistic_Investigation_on_C_C_Bond_Cleavage_of_Anthraquinone_Catalyzed_by_an_Atypical_Nonheme_Iron-Dependent_Dioxygenase_BTG13/24935729

المؤلفون: Huixuan Zhang, Long Chen, Penghui Du, Fan Li, Wen Liu

مصطلحات موضوعية: Biochemistry, Microbiology, Biotechnology, Developmental Biology, Infectious Diseases, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, typical emerging contaminant, sup >•, primary reactive species, organic wastewater treatment, molecular orbital level, hydrogen atom abstraction, electron transfer reaction, different reaction mechanisms, molecular orbital analysis, attacking organic pollutants, two alkoxy radicals, somo , 3 , similar radical self, radicals cannot react, n , alkoxy radicals, e <, reaction mechanism, n orbitals, dynamic analysis

Relation: https://figshare.com/articles/journal_contribution/Unraveling_Different_Reaction_Characteristics_of_Alkoxy_Radicals_in_a_Co_II_-Activated_Peracetic_Acid_System_Based_on_Dynamic_Analysis_of_Electron_Distribution/25148421

الاتاحة: https://doi.org/10.1021/acs.est.3c07977.s001
https://figshare.com/articles/journal_contribution/Unraveling_Different_Reaction_Characteristics_of_Alkoxy_Radicals_in_a_Co_II_-Activated_Peracetic_Acid_System_Based_on_Dynamic_Analysis_of_Electron_Distribution/25148421

المؤلفون: Wenjuan Zhu, Peng Wu, Virginia A. Larson, Akhilesh Kumar, Xiao-Xi Li, Mi Sook Seo, Yong-Min Lee, Binju Wang, Nicolai Lehnert, Wonwoo Nam

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Molecular Biology, Biotechnology, Infectious Diseases, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, singly occupied π, provides direct insight, mcd spectroscopy plays, interactions varies depending, hydrogen atom abstraction, dft analysis shows, superoxo frontier orbital, >- tmc ), 3 , 2 , 1 , ring size effects, mononuclear nonheme iron, >- tmc ligands, >- tmc ligand, 2 , overall fe –, ring size, n <, superoxo character, peroxo ligand, overall donicity

Relation: https://figshare.com/articles/journal_contribution/Electronic_Structure_and_Reactivity_of_Mononuclear_Nonheme_Iron_Peroxo_Complexes_as_a_Biomimetic_Model_of_Rieske_Oxygenases_Ring_Size_Effects_of_Macrocyclic_Ligands/24905322

الاتاحة: https://doi.org/10.1021/jacs.3c08559.s001
https://figshare.com/articles/journal_contribution/Electronic_Structure_and_Reactivity_of_Mononuclear_Nonheme_Iron_Peroxo_Complexes_as_a_Biomimetic_Model_of_Rieske_Oxygenases_Ring_Size_Effects_of_Macrocyclic_Ligands/24905322

المؤلفون: Michael T. Robo (1342344), Dimitris Collias (6443288), Paul M. Zimmerman (1275564)

مصطلحات موضوعية: Biophysics, Biochemistry, Cell Biology, Neuroscience, Biotechnology, Cancer, Hematology, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, reaction pathway optimization, potential energy surface, effective tensile strength, cogef method show, mechanochemical chain scission, describing chain scission, hydrogen atom abstraction, mechanical bond scission, bond scission geometries, polymer also becomes, bond scission, unactivated polymer, radical abstraction, scissile bond, bond rupture, bond activation, radical attack, radical activation, qualitatively incapable, overall beneficial, operate together

Relation: https://figshare.com/articles/journal_contribution/Interplay_Between_Applied_Force_and_Radical_Attack_in_the_Mechanochemical_Chain_Scission_of_Poly_acrylic_acid_/19068408

الاتاحة: https://doi.org/10.1021/acs.jpca.1c08919.s006

المؤلفون: Shiqing Zhang (652535), Xinyi Li (1778476), Yijing Wang (227101), Jingjing Wei (478970), Xue Zhang (166886), Yongjun Liu (291644)

مصطلحات موضوعية: Biophysics, Biochemistry, Biotechnology, Cancer, Infectious Diseases, Computational Biology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, resolution crystal structure, prior electron transfer, biochemical evidence showed, mutant study indicates, molecular mechanical calculations, peroxygenase mechanism catalyzed, hydrogen atom abstraction, hemoglobin dehaloperoxidase involved, peroxygenase mechanism, hemoglobin dehaloperoxidase, quantum mechanical, computational study, triggered either, titratable residues, quartet state, previously suggested, porphyrin group, multifunctional hemoprotein, limiting step, hydroxyl group, feasibility depends

Relation: https://figshare.com/articles/journal_contribution/Computational_Study_of_the_Peroxygenase_Mechanism_Catalyzed_by_Hemoglobin_Dehaloperoxidase_Involved_in_the_Degradation_of_Chlorophenols/19071256

الاتاحة: https://doi.org/10.1021/acs.inorgchem.1c03721.s001

المؤلفون: Linda Quach (7451132), Subhabrata Dutta (848578), Philipp M. Pflüger (8882366), Frederik Sandfort (4452520), Peter Bellotti (6639569), Frank Glorius (1555042)

مصطلحات موضوعية: Biochemistry, Cell Biology, Biotechnology, Evolutionary Biology, Ecology, Cancer, Infectious Diseases, Computational Biology, regioselectivity switch presents, hydrogen atom abstraction, alkenes intrinsically follows, unactivated alkenes , markovnikov hydrofunctionalization hydrofunctionalization, unactivated alkenes, regioselective hydrofunctionalization, markovnikov rule, markovnikov hydrooxygenation, synthetic chemistry, selectively adds, oxidation protocol, methodology enlarges, major challenge, innovative reagent, initiated hydrooxygenation, indispensable mean, highly reactive, established hydroboration, electrophilic species, could serve, carefully designed

Relation: https://figshare.com/articles/journal_contribution/Visible-Light-Initiated_Hydrooxygenation_of_Unactivated_Alkenes_A_Strategy_for_Anti-Markovnikov_Hydrofunctionalization/19119103

الاتاحة: https://doi.org/10.1021/acscatal.1c05555.s001

المؤلفون: Qing Liu, Linhong Long, Pengchen Ma, Yingjie Ma, Xuebing Leng, Jie Xiao, Hui Chen, Liang Deng

المصدر: Cell Reports Physical Science, Vol 2, Iss 6, Pp 100454- (2021)

مصطلحات موضوعية: iron, nitrogen ligand, carbene ligand, metal-ligand multiple bond, hydrogen atom abstraction, imido, Physics, QC1-999

وصف الملف: electronic resource

Relation: http://www.sciencedirect.com/science/article/pii/S2666386421001545; https://doaj.org/toc/2666-3864

URL الوصول: https://doaj.org/article/18991d4d23174ebf8de4d259a911e438

المؤلفون: Emiel Dobbelaar (9862297), Christian Rauber (11268842), Thorsten Bonck (11268845), Harald Kelm (1527895), Markus Schmitz (11268848), Matina Eloïse de Waal Malefijt (11268851), Johannes E. M. N. Klein (11268854), Hans-Jörg Krüger (2103613)

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Molecular Biology, Physiology, Biotechnology, Hematology, Computational Biology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, H atom abstraction reactions, ligand sphere, peroxidation, bond dissociation, Functional Model Properties, Analogue Complexes, iron site, Rabbit Lipoxygenase Iron complexes, rabbit lipoxygenase, hydroxo, water ligand, Active Site, Theoretical investigations, water molecule, reactivity support, proton-coupled electron transfer me., hydrogen atom abstraction reactions, coordination shell, tetraazamacrocyclic ligand

Relation: https://figshare.com/articles/journal_contribution/Combining_Structural_with_Functional_Model_Properties_in_Iron_Synthetic_Analogue_Complexes_for_the_Active_Site_in_Rabbit_Lipoxygenase/15159599

الاتاحة: https://doi.org/10.1021/jacs.1c04422.s001

المؤلفون: Runze Mao (9039087), Srikrishna Bera (1508239), Aurélya Christelle Turla (11360632), Xile Hu (1349778)

مصطلحات موضوعية: Biophysics, Biochemistry, Medicine, Neuroscience, Biotechnology, Cancer, Mental Health, Hematology, Computational Biology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Information Systems not elsewhere classified, – h bond, methods either work, hydrogen atom abstraction, bond dissociation energy, alkyl radicals generated, aliphatic carboxylic acids, added organic compounds, catalyzed intermolecular functionalization, based functional groups, c ­( sp, functional groups, based somo, unactivated c, narrow set, large array, high value, efficient synthesis, diverse functionalization

Relation: https://figshare.com/articles/journal_contribution/Copper-Catalyzed_Intermolecular_Functionalization_of_Unactivated_C_sp_sup_3_sup_H_Bonds_and_Aliphatic_Carboxylic_Acids/16547479

الاتاحة: https://doi.org/10.1021/jacs.1c05874.s001

المؤلفون: Masazumi Tamura (1446379), Eiji Sagawa (11418209), Akira Nakayama (1353762), Yoshinao Nakagawa (1446376), Keiichi Tomishige (1446373)

مصطلحات موضوعية: Biophysics, Biochemistry, Biotechnology, Cancer, Chemical Sciences not elsewhere classified, radical center driven, providing high selectivity, obtaining unique catalysis, dft calculations indicate, hydrogen atom abstraction, 4 +, 3 +, h atom abstractor, 2 , h atom, n atom, hybrid catalysts, hybrid catalyst, homogeneous components, function like, experimental studies, electron transfer, cn group, catalytic performance

Relation: https://figshare.com/articles/journal_contribution/Hydrogen_Atom_Abstraction_by_Heterogeneous_Homogeneous_Hybrid_Catalyst_of_CeO_sub_2_sub_and_2_Cyanopyridine_via_Redox_of_CeO_sub_2_sub_for_C_H_Bond_Oxidation_with_Air/16601630

الاتاحة: https://doi.org/10.1021/acscatal.1c03757.s001

المؤلفون: G. Manonmani (7474661), L. Sandhiya (1826290), K. Senthilkumar (1711099)

مصطلحات موضوعية: Biophysics, Biochemistry, Molecular Biology, Cancer, Inorganic Chemistry, Infectious Diseases, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, state calculation performed, secondary organic aerosol, rate constant calculated, possible hydrogen atom, hydrogen atom abstraction, global warming potentials, c7 carbon atom, atmospheric reactive species, initiated oxidation reactions, favorable reaction pathway, 54 × 10, initiated reaction mechanism, different time horizons, i4 , 3 , 2 , x <, subsequent reactions, favorable intermediate, 54 h, · oh

Relation: https://figshare.com/articles/journal_contribution/Mechanism_Kinetics_and_Ecotoxicity_Assessment_of_OH-Initiated_Oxidation_Reactions_of_Sulfoxaflor/16974423

الاتاحة: https://doi.org/10.1021/acs.jpca.1c05030.s001

المؤلفون: Nikitas G. Malliaros (11046058), Ina D. Kellner (1348320), Thomas Drewello (1348314), Michael Orfanopoulos (1348311)

مصطلحات موضوعية: Biochemistry, Molecular Biology, Developmental Biology, Cancer, Infectious Diseases, Plant Biology, Environmental Sciences not elsewhere classified, Biological Sciences not elsewhere classified, Information Systems not elsewhere classified, 1- lactonyl -2-hydro, Bu 4 N, lactone, C 60, hydrogen atom abstraction process, deuterium-incorporated experiments, Decatungstate-Photocatalyzed Addition, reaction products, step functionalization, lactonyl radicals

Relation: https://figshare.com/articles/journal_contribution/Decatungstate-Photocatalyzed_Addition_of_Lactones_to_60_Fullerene/14877013

الاتاحة: https://doi.org/10.1021/acs.joc.1c00954.s001

المؤلفون: Sungho Bosco Han (10450753), Hafiz Saqib Ali (9333489), Sam P. de Visser (7860788)

مصطلحات موضوعية: Biophysics, Biochemistry, Biotechnology, Infectious Diseases, Computational Biology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, carbon starvation-induced protein D, lysine biodegradation pathway, theory study, Glutarate Hydroxylation, chemical properties, hydrogen atom abstraction pathways, rate constants, hydroxylation reaction, calculations show, glutarate activation, substrate entrance, C 3 positions, CsiD enzyme, product channel, C 2 position, cycle intermediates, site cluster model, gas phase, Computational Study, substrate binding pocket, Escherichia coli, substrate binding, glutarate hydroxylation pathways

Relation: https://figshare.com/articles/journal_contribution/Glutarate_Hydroxylation_by_the_Carbon_Starvation-Induced_Protein_D_A_Computational_Study_into_the_Stereo-_and_Regioselectivities_of_the_Reaction/14308726

الاتاحة: https://doi.org/10.1021/acs.inorgchem.0c03749.s001

المؤلفون: Anjali Patwardhan (10429695), Ritimukta Sarangi (1266243), Bojana Ginovska (2394157), Simone Raugei (249177), Stephen W. Ragsdale (1264635)

مصطلحات موضوعية: Biophysics, Biochemistry, Pharmacology, Biotechnology, Inorganic Chemistry, Hematology, Infectious Diseases, Plant Biology, Virology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sulfonate groups, Ni ion, hydrogen-atom abstraction reaction, AOM, CoMSSCoB bind, methane oxidation, substrate methyl-SCoM, MCR reactions emanate, cofactor F 430, Methyl-SCoM Reductase, electron transfer, canonical MCR mechanisms, Long-Range Electron Transfer Methyl., Substrate Binding, substrate-bound states, thiol group, hydrogen atom, disulfide CoMSSCoB, coenzyme B

Relation: https://figshare.com/articles/journal_contribution/Nickel_Sulfonate_Mode_of_Substrate_Binding_for_Forward_and_Reverse_Reactions_of_Methyl-SCoM_Reductase_Suggest_a_Radical_Mechanism_Involving_Long-Range_Electron_Transfer/14298426

الاتاحة: https://doi.org/10.1021/jacs.1c01086.s001

المؤلفون: Yu-Cheng Yeh (2015866), Hak Joong Kim (1952275), Hung-wen Liu (1279131)

مصطلحات موضوعية: Biophysics, Biochemistry, Molecular Biology, Ecology, Developmental Biology, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, mechanism, hydrogen atom incorporation, diol, SAM enzyme superfamily, hydrogen atom abstraction, dehydration, AprD 4

Relation: https://figshare.com/articles/journal_contribution/Mechanistic_Investigation_of_1_2-Diol_Dehydration_of_Paromamine_Catalyzed_by_the_Radical_i_S_i_Adenosyl_l_methionine_Enzyme_AprD4/14340385

الاتاحة: https://doi.org/10.1021/jacs.1c00076.s001

المؤلفون: Sodiq O. Waheed (8815907), Shobhit S. Chaturvedi (8815910), Tatyana G. Karabencheva-Christova (8199738), Christo Z. Christov (8199741)

مصطلحات موضوعية: Biophysics, Biochemistry, Genetics, Molecular Biology, Cancer, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, double-mutant form K 1299E, GS, OG, KIE, electron transfer mechanism, MD, TET 2 enzyme, Mutations Ten-eleven translocation, WT TET 2 influence, DNA, 5 mC substrate, activation barrier, TET 2, hydrogen abstraction distance, hydrogen atom abstraction, QM

Relation: https://figshare.com/articles/journal_contribution/Catalytic_Mechanism_of_Human_Ten-Eleven_Translocation_2_TET2_Enzyme_Effects_of_Conformational_Changes_Electric_Field_and_Mutations/14213939

الاتاحة: https://doi.org/10.1021/acscatal.0c05034.s001

المؤلفون: Ramalingam, Ajoy, Panigrahy, Snehasish, Fenard, Yann, Curran, Henry J., Heufer, Karl Alexander

المساهمون: German Research Foundation, Science Foundation Ireland

مصطلحات موضوعية: IGNITION DELAY-TIME, LAMINAR BURNING VELOCITIES, HYDROGEN-ATOM ABSTRACTION, RAPID COMPRESSION MACHINE, RATE CONSTANTS, SHOCK-TUBE, SPECIES MEASUREMENT, PROPENE OXIDATION, FLAME SPEEDS, N-HEPTANE

وصف الملف: application/pdf

Relation: Combustion And Flame; Ramalingam, Ajoy, Panigrahy, Snehasish, Fenard, Yann, Curran, Henry, & Heufer, Karl Alexander. (2021). A chemical kinetic perspective on the low-temperature oxidation of propane/propene mixtures through experiments and kinetic analyses. Combustion and Flame, 223, 361-375. doi:https://doi.org/10.1016/j.combustflame.2020.10.020; http://hdl.handle.net/10379/16443

الاتاحة: http://hdl.handle.net/10379/16443
https://doi.org/10.1016/j.combustflame.2020.10.020