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    المؤلفون: Bedyu6r86ryurt

    مصطلحات موضوعية: 我要和你在一起▷线上看完整版 " I Love You (2022)在线观看[1080P]高清电影

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    المؤلفون: Maria Seymour St. John

    المصدر: Infant Mental Health Journal

    مصطلحات موضوعية: justice reproductive, implicit bias, Principios para Trabajar con Infantes, 010501 environmental sciences, Criminology, implizite Verzerrung, 01 natural sciences, 0302 clinical medicine, 與嬰兒丶兒童和家庭一起工作的多元化知情原則 (©Irving Harris Foundation), Developmental and Educational Psychology, 030212 general & internal medicine, Sociology, Intersectoral Collaboration, Niños y Familias Basados en la Diversidad, (© Fundación Irving Harris), media_common, Infant mental health, 交差性, Human rights, Articles, 交叉性, Health equity, Call to action, Psychiatry and Mental health, Préceptes de travail avec les nourrissons, les enfants et les familles basés sur la diversité (© Irving Harris Foundation), Mental Health, justicia reproductiva, Intersektionalität, 乳幼児・子ども・家族のための多様な情報に基づいた信条 (©アーヴィング・ハリス財団), مبادئ التنوع المستنيرة للعمل مع الرضع والأطفال والأسر (© مؤسسة إيرفينغ هاريس)؛ التحيز الضمني, von Diversität geprägte Grundsätze für die Arbeit mit Säuglingen, Kindern und Familien (© Irving Harris Foundation), media_common.quotation_subject, préjugés implicites, Public Policy, Developmental Science, Article, reproduktive Gerechtigkeit, Injustice, 03 medical and health sciences, Social Justice, Humans, التقاطع, Infant Health, 0105 earth and related environmental sciences, prejuicios implícitos, العدالة الإنجابية, Intersectionality, diversity‐informed tenets for work with infants, children, & families, Reproductive Rights, 生殖の公平性, Infant, reproductive justice, Reproductive justice, 生殖公義, intersectionnalité, Pediatrics, Perinatology and Child Health, intersectionality, 潜在的偏り, 隱性偏見

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    Dissertation/ Thesis

    المؤلفون: 陳甚安, Chen, Shen-An

    المساهمون: 何萬順, Her, One-Soon

    وصف الملف: 3132799 bytes; application/pdf

    Relation: Atknine, Victor 1997. The Evenki Language from the Yenisei to Sakhalin. In Shoji,Hiroshi & Janhunen, Juha (eds.). Northern Minority Languages: Problems of Survival, 109-121. Osaka, Japan: National Museum of Ethnology.\n\nBatu, Ali & Batu, Heysem. 2018. Historical Background of Turkish Gastronomy from ancient times to day. Journal of Ethnic Foods, 5(2), 76-82.\n\nBrunn, Stanley D & Toops, Stanley & Gilbreath, Richard. 2012. The Routledge Atlas of Central Eurasian Affairs. New York: Routledge.\n\nCornell, Svante E. 2011. Azerbaijan Since Independence. London: Routledge.\n\nEngesæth, Tarjei & Yakup, Mahire & Arienne, Dwyer. 2009. Greetings from the Teklimakan: a handbook of Modern Uyghur: Volume 1. Lawrence: University of Kansas Scholarworks.\n\nGil, David. 2013. Numeral Classifiers. The World Atlas of Language Structures Online ed. by Matthew S. Dryer & Martin Haspelmath, Chapter 55. Leipzig: Max Planck Institute for Evolutionary Anthropology. (Available online at\nhttp://wals.info/chapter/55, Accessed on 2019-11-20.)\n\nGöksel, Aslı & Kerslake, Celia. 2000. Studies on Turkish and Turkic Languages. Wiesbaden: Harrassowitz Verlag.\n\nHer One-Soon 2012. Distinguishing classifiers and measure words: A mathematical perspective and implications. Lingua 122.14: 1668-1691.\n\nHer, One-Soon and Bing-Tsiong Li. To appear. A Single origin of numeral classifiers in Asia and Pacific: A hypothesis. To appear in Marc Tang & Marcin Kilarski\n(eds.), Nominal Classification in Asia: Functional and Diachronic Perspectives. John Benjamins.\n\nJanhunen, Juha. 2000. Grammatical gender from east to west. Gender in Grammar and Cognition, part II: Manifestations of Gender ed. by Barbara Unterbeck, Matti Rissanen, Terttu Nevalainen & Mirja Saari, 689-797. Berlin & New York:\nMouton de Gruyter.\n\nJanhunen, Juha. 2003. The Mongolic Languages. London: Routledge.\n\nJohanson, Lars & CsatÓ, Éva Á. 1998. The Turkic Languages. London: Routledge.\n\nKavitskaya, Darya. 2010. Crimean Tatar. Languages of the world: Materials 477. Muenchen:\nLincom Europa.\n\nKornfilt, Jaklin & Heusinger, Klaus von. 2009. Specificity and Partitivity in some Altaic Languages. In Shibagaki, R and Vermeulen, R (Eds.), Proceedings of the 5th Workshop\non Formal Altaic Linguistics, MIT Working Papers in Linguistics, 19-40 MIT Press.\n\nLee, S. N. 2008. A grammar of Iranian Azerbaijani. Seoul: Thaehaksa.\n\nLehmann, Christian. 2015. Thoughts on grammaticalization. Berlin: Language Science Press.\n\nMahootian, Shahrzad. 1997. Persian Descriptive Grammars. London: Routledge.\n\nMansur, Salih. 2018. Crimean Tatar Language; Past, Present, and Future Unpublished manuscript\nLaGuardia Community College.\n\nSağ, Yağmur. 2018. The semantics of Turkish numeral constructions. Proceedings of Sinn Und Bedeutung, 22(2), 307-324. Retrieved from https://ojs.ub.unikonstanz.de/sub/index.php/sub/article/view/108\n\nSchaaik, Gerjan van. 1996. Studies in Turkish Grammar Turcologica. Wiesbaden: Harrassowitz Verlag.\n\nSchwarz, Henry G. 1984. The Minorities of Northern China: A Survey. Bellingham: Western Washington University Press.\n\nSlater, Keith W. 2003. A Grammar of Mangghuer. London: Routledge.\n\nStilo, Don. 2018. Numeral classifier systems in the Araxes-Iran linguistic area. In McGregor, William B & Wichmann, Søren (Eds.), The Diachrony of Classification Systems, 135-164. Amsterdam: John Benjamins Publishing Company.\n\nUnderhill, Robert. 1980. Turkish grammar. Cambridge, Mass. u.a: MIT Pr.\n\n步連增. 2011.〈漢語名量詞起源再探〉,《濟南學報哲學社會科學版》 2011.1:89-96。\n\n馬偉. 2009.〈語言接觸與撒拉語的變化〉,《青海民族學院學報社會科學版》 3.35: 29-35。\n\n李樹蘭、仲謙. 1986. 《錫伯語簡志》。 北京 : 民族出版社。\n\n林連雲. 1985. 《撒拉語簡志》。 北京 : 民族出版社。\n\n劉景憲、趙阿平、趙金純. 1997.《滿語研究通論》。 黑龍江省 : 黑龍江朝鮮民族出版社。\n\n耿世民、李增樣. 1985. 《哈薩克語簡志》。 北京 : 民族出版社。\n\n韓啟昆. 1994. 〈錫伯族西遷戍邊路線圖 解〉,《滿族研究》1994.2 : 90-94。\n\n胡增益. 1986.《鄂溫克語簡志》。北京 : 民族出版社。\n\n胡增益. 1994.《新滿漢大詞典》。新疆維吾爾自治區 : 新疆人民出版社。\n\n何萬順、林昆翰. 2015.〈分類詞與量詞的區分–以台灣地區華語為例〉,《漢語學報》2015.4 : 56-96。\n\n照那斯圖. 1981. 《土族語簡志》。 北京 : 民族出版社。\n\n仲素纯. 1982.《達斡爾語簡志》。 北京 : 民族出版社。\n\n趙相如. 1985.《維吾爾語簡志》。 北京 : 民族出版社。\n\n陳振宗、雷遠春. 1985. 《西部裕固語簡志》。 北京 : 民族出版社。\n\n陳振宗. 1986.《塔塔爾語簡志》。 北京 : 民族出版社。\n\n陳新義. 2015. 《中國北方阿爾泰語言語序類型研究》。北京:中國社會科學出版\n社。\n\n程適良、阿不都熱合曼. 1987. 《烏孜別克語簡志》。 北京 : 民族出版社。\n\n孫明. 2010. 〈關於漢語滿語量詞的比較研究〉,《民族翻譯》3.1 : 72-75。\n\n王慶鋒.2005. 《滿語研究》。 北京 : 民族出版社。\n\n歐南.烏珠爾. 2004.《達斡爾語概論》。黑龍江省。哈爾濱出版社。\n\n\n網路資源\nGippert, Jost. 2010.《TITUS印歐語系研究計劃網頁》。檢自\nhttp://titus.uni-frankfurt.de/indexe.htm?/texte/texte2.htm (Apr, 1, 2020) 。\n\nFobos92. 2013. 《阿爾泰語系分布圖》。檢自 https://commons.wikimedia.org/wiki/File:Lenguas_altaicas.png (Feb. 2, 2020) 。\n\nDörrbecker, Maximilian. 2011. 《蒙古語族分布圖》。檢自\nhttps://commons.wikimedia.org/wiki/File:Linguistic_map_of_the_Mongolic_languages.png (Apr, 1, 2020) 。; G0106555013; https://nccur.lib.nccu.edu.tw//handle/140.119/129646; https://nccur.lib.nccu.edu.tw/bitstream/140.119/129646/1/501301.pdf

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    Dissertation/ Thesis
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    Dissertation/ Thesis
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    المؤلفون: ABSTRACT This dissertation describes development of new synthetic organic transformations by using gold and copper salts. The use of these soft alkynophilic metals enables mild, diastereoselective and efficient transformations of a variety of readily available substrates to wide range of synthetically useful and biologically important N, O containing heterocyclic and carbocyclic products. For better understanding the thesis is divided into four chapters. The first chapter deals with the Gold-catalyzed oxidative cyclizations of cis-3-En-1-ynes to form cyclopentenone derivatives. The title reaction for synthesizing cyclopentenone derivatives utilizes a gold complex and 8-methylquinoline oxide as the catalyst system. The value of such reactions is reflected by their applicability to a broad range of benzene- and nonbenzene-derived substrates, thus giving various indanone and cyclopentenone derivatives, respectively. Such products are not attainable using diazocarbonyl reagents, as the gold carbenoids tend to react with C-H bonds. The second chapter deals with the gold-catalyzed oxidative cyclizations of 1,4-enynes were used to study the γ-effect on the Wagner–Meerwein rearrangement. Both experimental and theoretical work disclose that a gold substituent in the γ-position can direct a stereospecific 1,2 shift of the anti-β-substituent regardless of its intrinsic properties. The third chapter describes gold-catalyzed reactions of 3,5- and 3,6-dienynes with 8-alkyl- quinoline oxides results in an oxidative cycloaddition with high stereospecificity, this process involves a catalytic activation of a quinoline framework. The reaction mechanism involves the intermediacy of α-carbonyl pyridinium ylides (I) in a concerted 3+2 -cycloaddition with a tethered alkene. The fourth chapter presents the work aim at one-step construction of complex and important molecular frameworks via Cu-catalyzed oxidations of cheap tertiary amines. Cu-catalyzed aerobic oxidations of N-hydroxyaminopropenes to form C2-symmetric N- and O-functionalized cyclohexanes., en

    مصطلحات موضوعية: SATISH MADHAV GHORPADE, 簡介 本文介紹了利用金與銅的鹽類合成新型有機轉換化反應的發展。使用軟alkynophilic金屬使廣泛的各種各樣的現成的基質進行溫和的、非鏡像選擇性和高效轉換來合成生物學上重要的含氮雜環產物。為了更好地理解,本文分為四個章節。 第一章論述了cis-3-En-1-ynes的金催化氧化環化反應產生環戊烯酮衍生物。用於合成環戊烯酮衍生物的此反應使用了金錯合物和8-甲基??氧化物作為催化劑基底。這類反應適用於範圍廣泛的苯環和非苯環衍生的起始物,從而得到各種?酮和環戊烯酮衍生物。欲獲得這類的產物不能使用與diazocarbonyl試劑一同反應,因為金的碳烯化合物往往與碳氫鍵進行反應。 第二章討論1,4–烯炔類的金催化氧化環化反應被用來研究Wagner–Meerwein重排的γ效應。實驗和理論預測都證實了金的取代基中的γ位置可以導引抗 anti-β-取代基進行立體位向確定的1,2移位,而無視其固有特性。 第三章介紹了3,5-和3,6-dienynes金催化的反應與8-烷基??氧化物產生氧化環高立體位向選擇性,這個過程涉及??架構的催化活性。其反應機制包括α-羰基?啶?內鹽(I)的中間產物與拘束的烯烴類一起產生的[3+2]-環加成反應。 第四章所介紹的研究目的是利用廉價的叔胺類化合物的銅催化氧化反應進行一步的合成複雜而重要的分子結構。N-hydroxyaminopropenes經由銅催化的含氧的氧化反應形成具有C2對稱並含氮和氧的官能化環己烷。

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    المؤلفون: The low-valent and low-coordinate quintuply-bonded dichromium complex, (OEt2)KCr(κ1:κ2-N2Ndipp) 2 (1) was supported by the sterically hindered three-nitrogen donor ligand, Li2 N2Ndipp (N2Ndipp= 4-methyl-2,6-(NDipp)2pyridine) (Dipp = 2, 6-iPr2-C6H3). Treatment of 1 with 1 equiv of CaI2 leads to the formation of the hetereotrinuclear metal complex, {Ca(THF)2Cr2 μ3-κ1:κ2-(N2Ndipp)2 } (2), with the Cr-Cr quintuple bond retained. Treatment of 2 with organic azides gives Cr imido complexes. Reaction of 2 with p-tolyl azide gives {Ca Cr(p-tolylN)(μ-p-tolylN) 2 μ3-κ1:κ2-(N2Ndipp)2 } (4), in which two imido groups bridge and two imido groups chelate to chromium atoms. Treatment of 2 with trimethylsilyl azide produces the complex, {(μ-THF) Cr2Ca(μ-TMSN)2 μ3-κ1:κ2-(N2Ndipp)2 } (5). Reaction of 2 with 1-adamantyl azide generates the complex, {Ca(1AdN)Cr(μ-1AdN)2Cr μ3-κ1:κ2-(N2Ndipp)2 } (6). For comparison, we carry out the reaction of 1 with YbI2(THF)2 to give rise to the formation of {Yb(THF)2Cr2 μ3-κ1:κ2-(N2Ndipp)2 } (3), which is confirmed by the 1H NMR spectroscopy. Treatment of 3 with trimethylsilyl azide leads to the isolation of { YbCr2(μ-TMSN)3 μ3-κ1:κ2-(N2Ndipp)2 } (7), which is structurally similar to 5. The three metal centers of 5 and 7 are bound via the nitrogen atom of a trimethylsilyl imido group. Moreover, the bonding fashion of N2Ndipp in its product is transformed from bridging to chelating. In addition, treatment of 2 with diphenylzinc generates the complex, {(THF)Ca Cr(η1-C6H5) 2 μ3-κ1:κ2-(N2Ndipp)2 } (8), in which both phenyl rings are terminally coordinated to chromium atoms. The result is different from the carbozincation of alkynes and alkenes. In the second part of this thesis, treatment of Li2 N2Nmes (Mes = 2,4,6-CH3C6H2) with CrCl3 leads to the formation of Cr2 μ3-κ1:κ2-(N2Nmes)2 3 (9), where two Cr atoms are spanned by three N2Nmes ligands. However, we could not obtain the diamagnetic product upon reduction of 9. Afterwards, treatment of Li2 N2Nmes with CrCl2 generates the complex, { (Cl)Cr(μ-Cl)Cr(THF) μ3-κ1:κ2-(N2Nmes)2 } (10), in which two Cr atoms are ligated bridged by two N2Nmes ligands. Nevertheless, stepwise reduction of 10 generates orange intermediate, and then leads to the formation of 9. The isolation of the diamagnetic product is still not achieved., zh, en

    مصطلحات موضوعية: Chang, Ya-Hui, 本論文利用[N2Ndipp](N2Ndipp = 4-methyl-2,6-(NDipp)2pyridine)(Dipp = iPr2-C6H3)作為配基,將錯合物 [(OEt2)KCr(κ1:κ2-N2Ndipp)]2 (1)與碘化鈣反應,合成出含鈣的鉻-鉻五重鍵錯合物,{Ca(THF)2Cr2[μ3-κ1:κ2-(N2Ndipp)2]} (2),我們將2與小分子反應,可得到許多新穎的化合物。將2與多種有機疊氮小分子進行反應,其中,與對甲基苯疊氮反應,得到{Ca[Cr(p-tolylN)(μ-p-tolylN)]2[μ3-κ1:κ2-(N2Ndipp)2]} (4),分別有兩分子的對甲基苯亞胺基以橋接及端點的方式配位於雙鉻金屬上;與三甲基矽烷疊氮反應,則得到{(μ-THF)[Cr2Ca(μ-TMSN)2][μ3-κ1:κ2-(N2Ndipp)2]} (5),有兩分子的三甲基矽基亞胺基以橋接的方式鍵結於雙鉻金屬上;與1-金剛烷疊氮反應,則得到{Ca(1AdN)Cr(μ-1AdN)2Cr[μ3-κ1:κ2-(N2Ndipp)2]} (6),為兩分子的1-金剛烷亞胺基橋接於雙鉻金屬上,另有一分子的亞胺基配位於一鉻金屬上。之後,我們將1與YbI2(THF)2反應,得到{Yb(THF)2Cr2[μ3-κ1:κ2-(N2Ndipp)2]} (3),並且將此與三甲基矽烷疊氮反應,得到{[YbCr2(μ-TMSN)3][μ3-κ1:κ2-(N2Ndipp)2]} (7),此結構與錯合物5類似,且三金屬皆經由三甲基矽基亞胺基的氮原子橋接於一起。而後,將2與二苯基鋅反應,得到{(THF)Ca[Cr(η1-C6H5)]2[μ3-κ1:κ2-(N2Ndipp)2]} (8),為二苯基鋅的兩片苯環以端點的方式配位於雙鉻金屬上,與碳-碳多重鍵於有機合成反應常進行的碳-鋅加成反應不同。 將Li2[N2Nmes](mes = 2,4,6-(CH3)3C6H2)作為配基與氯化亞鉻進行反應,可以得到Cr2[μ3-κ1:κ2-(N2Nmes)2]3 (9),為三片配基橋接於雙鉻金屬上的結構。試圖將9進行還原,無法分離出逆磁性的產物,故我們將Li2[N2Nmes]與氯化鉻反應,得到{[(Cl)Cr(μ-Cl)Cr(THF)][μ3-κ1:κ2-(N2Nmes)2]} (10),為兩片配基橋接於雙鉻金屬上,其中,雙鉻金屬間有一氯原子橋接其中,另有一氯原子以端點方式鍵結於鉻金屬上。然而,我們將10進行還原,發現會先經過一橘色中間物,再經過9,最後得到褐色的產物,亦無法分離出可能為五重鍵的產物。